GIBBS FREE ENERGY

Relationship Between Free Energy of Reaction and Standard Free Energy of Reaction

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Definition of Gibbs Free Energy
Calculating the Change in Free Energy
Advantage of Using G compared to Suniverse
Predicting the Spontaneity of a System using Gibbs Free Energy
Effect of Temperature on G
Gibbs Free Energy of Formation
Physical Meaning of Free Energy of Formation
Relationship for Free Energy and Standard Energy of Reaction
Graphical Analysis of Free Energy of Formation
Additional Methods of Calculating G
Gibbs Free Energy and Electric Cell Potential
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IS THERE A RELATIONSHIP BETWEEN FREE ENERGY OF REACTION AND THE STANDARD FREE ENERGY OF A REACTION?

The relationship between the free energy of reaction at any moment in time (DG) and the standard-state free energy of reaction (DGo) is described by the following equation.

 

DG = DGo + RT ln Q

where

·        R – ideal gas constant (J/mol-K)

·        T  – temperature (K)

·        Q – reaction quotient at that moment in time

 

As we have seen, the driving force behind a chemical reaction is zero (DG = 0) when the reaction is at equilibrium (Q = K). [2]

 

DGo = - RT ln K

Sources:
 
4 Foulkes, F.R. Welcome to Phys Chem. University of Toronto.  Sept 2003.